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CHM 101 CHM 101 Past Questions Objective Question

Question

Nitric oxide reacts with hydrogen to form nitrous oxide, and water. Use the following data to determine the rate equation for the reaction 2NO + H₂ → N₂O + H₂O. Data: Expt 1: [NO]=0.021, [H₂]=0.065, Rate=1.46; Expt 2: [NO]=0.021, [H₂]=0.260, Rate=1.46; Expt 3: [NO]=0.042, [H₂]=0.065, Rate=5.84.
Options
A rate = k[NO]
B rate = k[NO]²
Correct Answer
C rate = k[NO][H₂]
D rate = k[NO]²[H₂]
Correct Answer

Option B is the correct answer.

Detailed Explanation

Comparing Expt 1 and 2: [NO] constant, [H₂] quadruples, rate unchanged → zero order in H₂. Comparing Expt 1 and 3: [H₂] constant, [NO] doubles, rate quadruples (1.46 to 5.84) → second order in NO. Rate = k[NO]².

Hint

Find how rate changes when each reactant's concentration is changed while the other is held constant.

Question Info