Question Detail
Question
Calculate the solubility product of 0.001 mol dm⁻³ solution of Ag₂S at 25 °C
Correct Answer
Option A is the correct answer.
Detailed Explanation
Ag₂S(s) ⇌ 2Ag⁺(aq) + S²⁻(aq). If solubility s = 0.001 M, then [Ag⁺] = 2s = 0.002 M, [S²⁻] = s = 0.001 M. Ksp = [Ag⁺]²[S²⁻] = (0.002)²(0.001) = (4×10⁻⁶)(1×10⁻³) = 4.0 × 10⁻⁹ mol³ dm⁻⁹.
Hint
Write the dissociation equation and relate ion concentrations to molar solubility.