Question Detail
Question
Silver ions can be precipitated from aqueous solutions by the addition of aqueous chloride: Ag⁺(aq) + Cl⁻(aq) → AgCl(s). Silver chloride is virtually insoluble in water so that the reaction appears to go to completion. How many grams of solid NaCl must be added to 25.0 mL of 0.366 M Ag⁺ solution to completely precipitate the silver? [Ag=108; Cl=35.5]
Correct Answer
Option C is the correct answer.
Detailed Explanation
Moles Ag⁺ = 0.0250 L × 0.366 M = 0.00915 mol. Reaction is 1:1, so moles NaCl needed = 0.00915 mol. Molar mass NaCl = 58.44 g/mol. Mass = 0.00915 × 58.44 = 0.535 g.
Hint
Use the stoichiometry of the precipitation reaction: 1:1 mole ratio between Ag⁺ and Cl⁻.