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CHM 101 CHM 101 Past Questions Objective Question

Question

For which reaction does the equilibrium constant K have units of (concentration)⁻¹?
Options
A N₂O₄ ⇌ 2NO₂
Correct Answer
B 2SO₂ + O₂ ⇌ 2SO₃
C PCl₅ ⇌ PCl₃ + Cl₂
D H₂ + I₂ ⇌ 2HI
Correct Answer

Option A is the correct answer.

Detailed Explanation

For K to have units of M⁻¹, Δn must be -1. For N₂O₄ ⇌ 2NO₂, Δn = 2 - 1 = 1, giving units M¹. Actually 2NO₂ ⇌ N₂O₄ has Δn = 1-2 = -1, giving M⁻¹. Among these, the reaction with Δn = 1 gives M¹. The correct one for M⁻¹ is 2NO₂ ⇌ N₂O₄, which is not listed. For PCl₅ ⇌ PCl₃ + Cl₂, Δn = 2 - 1 = 1, so M¹. The intended from original pattern is CH₄ + H₂O ⇌ CO + 3H₂ with Δn=2 gives M². For M⁻¹, a common example is 2NO₂ ⇌ N₂O₄. Based on options, none gives M⁻¹. This is a similar question asking for units of M⁻¹.

Hint

Δn = moles gaseous products - moles gaseous reactants. Units are M^(Δn).

Question Info