Question Detail

CHM 101 CHM 101 Past Questions Objective Question

Question

The compound CH₃CH₂CH=CH₂ reacts with HBr to give primarily:
Options
A CH₃CH₂CH₂CH₂Br
B CH₃CH₂CHBrCH₃
Correct Answer
C CH₃CHBrCH=CH₂
D CH₂BrCH₂CH=CH₂
Correct Answer

Option B is the correct answer.

Detailed Explanation

According to Markovnikov's rule, the hydrogen adds to the less substituted carbon of the double bond. For but-1-ene, the H adds to the terminal carbon, Br adds to the internal carbon, yielding 2-bromobutane.

Hint

The major product is the one where the halogen is on the more substituted carbon.

Question Info