Question Detail

CHM 102 Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry Objective Question

Question

Which alcohol has the highest boiling point for a given number of carbons?
Options
A 1-butanol
Correct Answer
B 2-butanol
C 2-methyl-2-propanol
D butane
Correct Answer

Option A is the correct answer.

Detailed Explanation

1-butanol is a straight-chain primary alcohol with the most surface area for intermolecular hydrogen bonding, giving a higher boiling point than branched isomers.

Hint

Less branching allows closer packing.

Question Info