Question Detail

CHM 102 Alkynes: Structure, Bonding, and Nomenclature Objective Question

Question

What is the major product of the hydration of 1-butyne (CH3CH2C≡CH) with HgSO4/H2SO4?
Options
A 1-Butanol
B 2-Butanol
C Butanone (methyl ethyl ketone)
Correct Answer
D Butanal
Correct Answer

Option C is the correct answer.

Detailed Explanation

Hydration of terminal alkynes gives methyl ketones via enol tautomerization. For 1-butyne, the product is butanone (CH3CH2COCH3).

Hint

Markovnikov addition of water gives an enol that tautomerizes to a ketone.

Question Info