Question Detail

CHM 102 Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis Objective Question

Question

What is the product when an aromatic primary amine (aniline) is treated with nitrous acid at 0-5°C?
Options
A Phenol
B Benzenediazonium salt (stable at low temperature)
Correct Answer
C Nitrosoamine
D Azobenzene
Correct Answer

Option B is the correct answer.

Detailed Explanation

Aromatic primary amines react with HNO2 at low temperature to form relatively stable diazonium salts (ArN2+ X-), which are important intermediates for azo dyes.

Hint

Arenediazonium salts are stable at 0-5°C.

Question Info