Question Detail

CHM 102 Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis Objective Question

Question

Which of the following amines has the highest boiling point for similar molecular weight?
Options
A CH₃CH₂CH₂NH₂ (1° amine)
Correct Answer
B (CH₃)₂CHNH₂ (1° branched)
C (CH₃CH₂)₂NH (2° amine)
D (CH₃)₃N (3° amine)
Correct Answer

Option A is the correct answer.

Detailed Explanation

Primary and secondary amines can form intermolecular hydrogen bonds (N-H···N), increasing boiling points. Tertiary amines lack N-H bonds and have lower boiling points.

Hint

N-H bonds allow hydrogen bonding.

Question Info