Question Detail

CHM 102 Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis Objective Question

Question

What is the product when a secondary aliphatic amine reacts with nitrous acid (HNO₂)?
Options
A Alcohol
B N-Nitrosoamine (yellow oil)
Correct Answer
C Diazonium salt
D No reaction
Correct Answer

Option B is the correct answer.

Detailed Explanation

Secondary amines react with HNO₂ to form N-nitrosoamines (R₂N-N=O), which are usually yellow oils and are potent carcinogens.

Hint

Nitroso group attaches to nitrogen.

Question Info