Question Detail

CHM 102 Carbonyl Compounds Objective Question

Question

What is the Cannizzaro reaction?
Options
A Oxidation of a primary alcohol to aldehyde
B Disproportionation of an aldehyde without α-hydrogens in concentrated base to an alcohol and a carboxylic acid
Correct Answer
C Reduction of a ketone to alcohol
D Addition of Grignard to carbonyl
Correct Answer

Option B is the correct answer.

Detailed Explanation

The Cannizzaro reaction: aldehydes with no α-hydrogens (e.g., formaldehyde, benzaldehyde) undergo disproportionation in concentrated base to give an alcohol and a carboxylic acid salt.

Hint

Alone → alcohol + acid.

Question Info