Question Detail

CHM 102 Qualitative and Quantitative Analysis in Organic Chemistry Objective Question

Question

What indicates the presence of nitrogen in Lassaigne's extract?
Options
A Yellow precipitate with AgNO₃
B Prussian blue coloration with FeSO₄ and FeCl₃
Correct Answer
C Black precipitate with lead acetate
D Purple color with sodium nitroprusside
Correct Answer

Option B is the correct answer.

Detailed Explanation

Nitrogen in the extract forms NaCN, which reacts with Fe²⁺ to form ferrocyanide, then with Fe³⁺ to give Prussian blue [Fe₄(Fe(CN)₆)₃].

Hint

Deep blue color.

Question Info