Question Detail

CHM 102 Qualitative and Quantitative Analysis in Organic Chemistry Objective Question

Question

In UV-Vis spectroscopy, what happens to λmax as conjugation increases?
Options
A λmax decreases (shifts to shorter wavelength)
B λmax increases (shifts to longer wavelength)
Correct Answer
C No change
D Becomes negative
Correct Answer

Option B is the correct answer.

Detailed Explanation

Increased conjugation lowers the HOMO-LUMO gap, causing absorption at longer wavelengths (higher λmax, bathochromic shift).

Hint

More conjugation = red shift.

Question Info