Question Detail

CHM 102 Practice Questions Objective Question

Question

Which halogen does not appreciably react with methane in a free-radical substitution reaction?
Options
A chlorine
B bromine
C iodine
Correct Answer
D fluorine
Correct Answer

Option C is the correct answer.

Detailed Explanation

Iodine does not appreciably react with methane in free-radical substitution because the reaction is thermodynamically unfavorable (endothermic). The I-I bond is weak, but the H-I bond formed is also weak, making the overall reaction not favorable.

Hint

Which halogen has the weakest H-X bond formed?

Question Info