Question Detail

CHM 102 Practice Questions Objective Question

Question

Which of the following correctly ranks the cycloalkanes in order of increasing ring strain per methylene?
Options
A cyclopropane < cyclobutane < cyclohexane < cycloheptane
B cyclohexane < cyclopentane < cyclobutane < cyclopropane
Correct Answer
C cyclopentane < cyclobutane < cyclopentane < cyclopropane
D cyclopentane < cyclopropane < cyclobutane < cyclohexane
Correct Answer

Option B is the correct answer.

Detailed Explanation

Ring strain per CH2 increases with decreasing ring size (except cyclopropane has the most). The correct order of increasing ring strain is: cyclohexane < cyclopentane < cyclobutane < cyclopropane. Cyclohexane is almost strain-free, and cyclopropane has the most strain.

Hint

Which cycloalkane has the least ring strain, and which has the most?

Question Info