Question Detail

CHM 102 Practice Questions Objective Question

Question

Which of the following compounds reacts fastest with HBr?
Options
A 1-propanol
B 2-methyl-1-propanol
C 2-propanol
D 2-methyl-2-propanol
Correct Answer
Correct Answer

Option D is the correct answer.

Detailed Explanation

2-Methyl-2-propanol (tert-butyl alcohol, tertiary) reacts fastest with HBr because it forms the most stable tertiary carbocation. The reactivity order with HX is: tertiary > secondary > primary.

Hint

Which alcohol forms the most stable carbocation?

Question Info