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CHM 102 Practice Questions Objective Question

Question

Which of the following functional group series is ranked according to increasing boiling points?
Options
A diethyl ether, ethane, ethanol, ethanethiol
B ethane, ethanol, diethyl ether, ethanethiol
C ethane, diethyl ether, ethanethiol, ethanol
Correct Answer
D diethyl ether, ethane, ethanethiol, ethanol
Correct Answer

Option C is the correct answer.

Detailed Explanation

For comparable molecular weights, boiling points increase in the order: alkanes < ethers < thiols < alcohols. This reflects increasing strength of intermolecular forces: van der Waals < dipole-dipole < dipole-dipole + weak H-bonding < strong H-bonding.

Hint

How do different functional groups compare in boiling point?

Question Info