Question Detail
Question
Thiols are alcohol analogs in which the oxygen has been replaced by sulfur (e.g., CH3SH). Given the fact that the S–H bond is less polar than the O–H bond, which of the following statements comparing thiols and alcohols is correct?
Correct Answer
Option A is the correct answer.
Detailed Explanation
Since the S-H bond is less polar than O-H, thiols form weaker hydrogen bonds than alcohols. This results in lower boiling points for thiols compared to alcohols of similar molecular weight.
Hint
How does bond polarity affect hydrogen bonding strength?