Question Detail
Question
An unknown compound gave a positive Tollens' test. Treatment of the unknown with I2/NaOH gave a solid which was identified as iodoform. The unknown was?
Correct Answer
Option A is the correct answer.
Detailed Explanation
The compound gave a positive Tollens' test (aldehyde) and positive iodoform test (CH3CO- group). Ethanal (acetaldehyde, CH3CHO) is an aldehyde with the CH3CO- group (after oxidation) and gives both tests. Acetone gives iodoform but not Tollens'. Propanal gives Tollens' but not iodoform.
Hint
Which aldehyde has the CH3CO- group?