Question Detail

CHM 102 Sblock elements Objective Question

Question

What is the primary reason that metals in the lower half of Group 1 tend to form more complicated oxides (peroxides and superoxides) as opposed to simple oxides?
Options
A They have smaller metal ions with higher charge density, leading to greater polarization.
B The formation of simple oxides is energetically unfavorable for larger ions.
C The larger metal ions have a low charge density, which prevents them from polarizing complicated oxide ions to destruction, thus making the complicated oxides energetically stable.
Correct Answer
D They react directly with atmospheric nitrogen, preventing simple oxide formation.
Correct Answer

Option C is the correct answer.

Detailed Explanation

Page 9 explains: 'The formation of more complicated oxides (i.e. peroxides and superoxides) from the metals releases more energy and makes the system more energetically stable.' It further clarifies: 'This is true for the metals in the lower half of the group where the metal ions are big and have a low charge density.' and 'At the top of the group, the small ions with a higher charge density tend to polarize the more complicated oxide ions to the point of destruction. Therefore, they only form simple oxides.' This indicates that for larger ions with low charge density, complicated oxides are stable.

Hint

Consider the concepts of charge density and polarization mentioned on page 9 in relation to ion size.

Question Info