Question Detail

CHM 102 P block elements Objective Question

Question

Unlike carbon, silicon primarily forms chains of Si-O-Si-O rather than catenating extensively in Si-Si-Si chains. What special feature of carbon allows it to catenate more readily?
Options
A Smaller atomic size of Carbon
Correct Answer
B Higher electronegativity of Carbon
C Ability of Carbon to form pi (π) bonds
D Inability of Carbon to expand its octet
Correct Answer

Option A is the correct answer.

Detailed Explanation

Page 24 notes that 'Carbon can catenate. (forms -C-C-C- C- chains) Silicon forms only Si-O-Si-O chains in silica SiO₂.' While the document doesn't explicitly state why carbon catenates more, the smaller size and stronger C-C bonds are key. The other options are either not directly related to catenation (pi bonds affect multiple bonding, not necessarily linear chain formation directly), or are a consequence rather than the cause.

Hint

Consider the bond strength and atomic size for catenation.

Question Info