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CHM 101 CHM 101 Past Questions Objective Question

Question

What is the effect of increasing temperature on a reaction where ΔH > 0 and ΔS < 0?
Options
A Reaction becomes more spontaneous
B ΔG decreases
C Reaction becomes less spontaneous
Correct Answer
D Entropy becomes positive
Correct Answer

Option C is the correct answer.

Detailed Explanation

For ΔH > 0 and ΔS < 0, the equation ΔG = ΔH - TΔS shows that the -TΔS term is positive (since ΔS is negative). As T increases, this positive term becomes larger, making ΔG more positive and the reaction less spontaneous.

Hint

Plug the signs into ΔG = ΔH - TΔS. What happens to ΔG as T increases?

Question Info