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CHM 101 CHM 101 Past Questions Objective Question

Question

If ΔH is positive and ΔS is negative, the reaction is:
Options
A Always spontaneous
B Never spontaneous
Correct Answer
C Spontaneous at low temperatures
D Spontaneous at high temperatures
Correct Answer

Option B is the correct answer.

Detailed Explanation

From ΔG = ΔH - TΔS, if ΔH > 0 and ΔS < 0, then both terms are positive (ΔH is positive, and -TΔS is positive because ΔS is negative). Therefore, ΔG will be positive at all temperatures, and the reaction is never spontaneous.

Hint

Analyze the signs in the Gibbs free energy equation. Is it possible for ΔG to be negative?

Question Info