Question Detail

CHM 101 CHM 101 Past Questions Objective Question

Question

In a reaction between CH₃CH₂CH=CH₂ and HBr, the Markovnikov's product is?
Options
A CH₃CH₂CHBrCH₃
Correct Answer
B CH₃CH₂CH₂CH₂Br
C CH₃CH₂CH=CHBr
D CH₃CH₂CBr=CH₂
Correct Answer

Option A is the correct answer.

Detailed Explanation

Markovnikov's rule states that the hydrogen adds to the carbon with the greater number of hydrogens. For but-1-ene (CH₃CH₂CH=CH₂), the H adds to terminal carbon, Br adds to internal carbon, giving 2-bromobutane (CH₃CH₂CHBrCH₃).

Hint

The hydrogen adds to the less substituted carbon of the double bond.

Question Info