Question Detail

CHM 101 Quantum Theory and Atomic Structure Objective Question

Question

Which elements exhibit anomalous electron configurations due to the closeness of the 3d and 4s orbital energies?
Options
A Lithium and Beryllium
B Oxygen and Sulfur
C Chromium and Copper
Correct Answer
D Sodium and Potassium
Correct Answer

Option C is the correct answer.

Detailed Explanation

Chromium and copper exhibit anomalous electron configurations due to the closeness of the 3d and 4s orbital energies. Chromium prefers [Ar] 4s¹ 3d⁵ rather than [Ar] 4s² 3d⁴, and copper prefers [Ar] 4s¹ 3d¹⁰ rather than [Ar] 4s² 3d⁹. These configurations provide extra stability from half-filled or fully filled d subshells.

Hint

Recall which elements are commonly cited as exceptions to the standard filling order.

Question Info