Question Detail

CHM 101 Chemical Bonding and Intermolecular Forces Objective Question

Question

Why do larger molecules generally have higher boiling points due to London dispersion forces?
Options
A Larger molecules have stronger covalent bonds
B Larger atoms have more electrons that can be easily polarized, increasing the strength of dispersion forces
Correct Answer
C Larger molecules have permanent dipoles
D Larger molecules form hydrogen bonds
Correct Answer

Option B is the correct answer.

Detailed Explanation

Larger molecules (with greater molecular weight and more electrons) have larger electron clouds that are more easily polarized. This increased polarizability leads to stronger London dispersion forces, which require more energy to overcome, resulting in higher melting and boiling points.

Hint

More electrons mean more temporary dipoles and stronger attractions.

Question Info