Question Detail

CHM 102 Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis Objective Question

Question

Which of the following amines will NOT react with Hinsberg reagent (benzenesulfonyl chloride)?
Options
A Primary amine
B Secondary amine
C Tertiary amine
Correct Answer
D Aromatic primary amine
Correct Answer

Option C is the correct answer.

Detailed Explanation

Tertiary amines have no N-H bond and cannot form sulfonamides with Hinsberg reagent. Primary amines form soluble sulfonamides in base; secondary amines form insoluble sulfonamides.

Hint

No hydrogen on nitrogen to replace.

Question Info