Question Detail

CHM 101 Chemical Thermodynamics Objective Question

Question

When ΔH is positive and ΔS is positive, when is the reaction spontaneous?
Options
A Spontaneous at all temperatures
B Spontaneous only at low temperatures
C Spontaneous only at high temperatures
Correct Answer
D Nonspontaneous at all temperatures
Correct Answer

Option C is the correct answer.

Detailed Explanation

When ΔH is positive and ΔS is positive, ΔG = ΔH - TΔS becomes negative only at high temperatures where the TΔS term dominates. Thus, the reaction is spontaneous at high temperatures.

Hint

The notes provide a table summarizing these relationships.

Question Info