Question Detail

CHM 101 Chemical Thermodynamics Objective Question

Question

When ΔH is negative and ΔS is negative, when is the reaction spontaneous?
Options
A Spontaneous at all temperatures
B Spontaneous only at high temperatures
C Spontaneous only at low temperatures
Correct Answer
D Nonspontaneous at all temperatures
Correct Answer

Option C is the correct answer.

Detailed Explanation

When ΔH is negative and ΔS is negative, ΔG = ΔH - TΔS becomes negative only at low temperatures where the TΔS term is small. Thus, the reaction is spontaneous at low temperatures.

Hint

The notes provide a table summarizing these relationships.

Question Info