Questions (1999)

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1301
The carbon atom of a carbonyl group is
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1302
Which statement about the carbonyl group is NOT true?
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1303
Acetone contains
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1304
Formalin is
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1305
Which of the following will have the highest boiling point?
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1306
What property of low-molecular weight aldehydes and ketones accounts for the ma…
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1307
Primary alcohols have boiling points that are the corresponding aldehydes.
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1308
The melting points of aldehydes and ketones tend to :
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1309
Which action best accounts for the solubility of aldehydes and ketones in water?
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1310
Ketones are prepared by the oxidation of
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1311
Which of the following do you consider to be suitable for obtaining acetone (CH…
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1312
Cyclopentanol undergoes oxidation to give :
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1313
Which statement about the carbonyl group of ketones and aldehydes is true? I. I…
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1314
Acetone reacts with HCN to form a cyanohydrin. It is an example of
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1315
Which of the following reagents will react readily with both aldehydes and keto…
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1316
The reaction of ethanal with one equivalent of methanol and a trace of an acid …
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1317
Acetone undergoes reduction with hydrazine in the presence of NaOH to form prop…
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1318
Acetone undergoes reduction with zinc amalgam in HCl to form propane. This reac…
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1319
Cannizzaro reaction is not given by
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1320
When formaldehyde is treated with 50% NaOH solution, it undergoes
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1321
The reduction of a ketone
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1322
Reduction of acetaldehyde with H2/Ni gives
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1323
On reduction with LiAlH4, which of the following compounds could yield an optic…
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1324
The reduction of cyclohexanone with LiAlH4 (or NaBH4) will give
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1325
Aldehydes undergo oxidation with KMnO4/H+ to give
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1326
Oxidation of acetaldehyde with Na2Cr2O7/H+ gives
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1327
A hydrazone will result from the reaction of hydrazine with
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1328
Aldehydes can be distinguished from ketones by using
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1329
The appearance of a silver mirror in Tollens' test indicates the presence of :
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1330
Acetaldehyde on treatment with Tollens' reagent gives a precipitate of
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1331
Which of the following compounds will give a positive test with Fehling's solut…
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1332
Acetaldehyde on treatment with Fehling's solution gives a precipitate of
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1333
Which of the following compounds will give an iodoform test?
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1334
Which of the following compounds does not give a positive iodoform test :
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1335
Which of the following compounds does not give iodoform test on treatment with …
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1336
An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (A)…
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1337
An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (B)…
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1338
An unknown compound gave a positive Tollens' test. Treatment of the unknown wit…
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1339
Which of the following characterizes the reactions of aldehydes and ketones?
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1340
Why do aldehydes undergo nucleophilic addition reactions while esters undergo n…
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1341
Which of the following reagents can be used to reduce acetaldehyde to ethyl alc…
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1342
What is the hybridization of the carbonyl oxygen in carboxylic acids?
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1343
What is the hybridization and geometry of the carbonyl carbon in carboxylic aci…
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1344
Organic compound (A), C4H8O, does not react with sodium or PCl5. However, it re…
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1345
Check the incorrect statement :
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1346
In the conversion of wine to vinegar
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1347
Vinegar is a
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1348
In succinic acid, HOOC(CH2)nCOOH, n is equal to
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1349
In adipic acid, HOOC(CH2)nCOOH, n is equal to
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1350
The compound in which hydrogen bonding is not possible is
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1351
Which compound has the highest boiling point?
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1352
When carboxylic acids and dicarboxylic acids have similar molecular weights, ho…
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1353
The greater acidity of carboxylic acids compared to alcohols arises primarily f…
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1354
Which of the following statements is false about the acid-strength of acetic ac…
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1355
Arrange the following compounds in order of decreasing acidity :
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1356
Which of the following is the strongest acid in aqueous solution?
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1357
Which is the strongest acid?
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1358
Which of the following compounds is most acidic?
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1359
Which of the following compounds is the strongest acid?
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1360
Which of the following will give acetic acid on acid-hydrolysis?
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1361
Propanenitrile undergoes acid-hydrolysis to give
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1362
The characteristic reaction of carboxylic acids is :
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1363
Which of the following compounds will react with Tollens' reagent to give metal…
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1364
Which of the following compounds on treatment with NaHCO3 will liberate CO2?
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1365
Which of the following reagents will convert acetic acid into acetyl chloride?
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1366
Butyric acid reacts with PCl5 to give
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1367
Acetic acid undergoes reduction with LiAlH4 to give
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1368
Acetic acid reacts with methyl alcohol in the presence of an acid catalyst to g…
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1369
Calcium acetate on strong heating gives
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1370
CH3(CH2)4COONa is the sodium salt of hexanoic acid. The water solubility of thi…
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1371
Which of the following compounds has the lowest boiling point?
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1372
Which of the following is the correct ranking in decreasing order of relative B…
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1373
Acetyl chloride undergoes nucleophilic substitution at a faster rate than methy…
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1374
Esters and amides are most easily made by nucleophilic acyl substitution reacti…
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1375
Which of the following conditions will drive the equilibrium of the Fischer est…
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1376
Which of the following statements describes the first step in the mechanism of …
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1377
Ammonium acetate on strong heating gives
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1378
Which reaction does not yield an ester as one of the products?
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1379
Silver acetate reacts with Br2 to form methyl bromide, carbon dioxide, and AgBr…
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1380
Hunsdiecker reaction is used for the preparation of
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1381
A compound undergoes reduction with LiAlH4. It also dissolves in aqueous NaOH f…
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1382
Acid chlorides undergo reduction to the corresponding aldehydes on treatment wi…
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1383
Acetic anhydride is obtained by the reaction of :
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1384
Acetic anhydride reacts with ethanal to give
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1385
Acetamide on heating with P2O5 gives :
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1386
Acetamide is a much weaker base than ammonia. This is because
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1387
Which of the following statements is False about acetamide?
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1388
The C—C—O bond angle in is approximately
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1389
Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and am…
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1390
Which of the following acid-derivatives are most stable?
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1391
Acetamide can be converted into methylamine by
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1392
Acetamide on reduction with LiAlH4 gives
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1393
Amides undergo hydrolysis under acidic conditions to give
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1394
By which of the following methods can CH3CONH2 be converted to CH3CN?
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1395
Which of the following reagents will react with acetamide to form methylamine?
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1396
Which of the following compounds does not form a salt with dilute HCl?
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1397
Propionamide on heating with a mixture of bromine and sodium hydroxide gives
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1398
What happens when urea is treated with hydrazine?
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1399
Carbonyl chloride reacts with ammonia to give
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1400
Which of the following is not a constituent of normal urine?
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