Questions (2006)

# Question Topic Actions
1201
Which reagent is commonly used to reduce amides to amines?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1202
The carbylamine test (isocyanide test) is used to detect:
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1203
In the carbylamine reaction, what is the product when methylamine reacts with C…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1204
What type of hybridization does the nitrogen atom have in a typical amine?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1205
Which of the following amines has the highest boiling point for a similar molec…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1206
Why are amines soluble in water?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1207
What is the product when a primary amine reacts with nitrous acid (HNO2)?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1208
What is the product when a secondary aliphatic amine reacts with nitrous acid (…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1209
Tertiary aliphatic amines react with nitrous acid to form:
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1210
Why are aliphatic amines stronger bases than aromatic amines like aniline?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1211
Which of the following is the strongest base?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1212
What is the approximate pKb range for aliphatic amines?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1213
What is the product of the reaction between an amine and a carboxylic acid?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1214
What is the IUPAC name for (CH3CH2)2NH?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1215
In the Gabriel synthesis, phthalimide is used to prepare:
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1216
What is the product of exhaustive methylation of a tertiary amine with excess C…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1217
Which of the following is NOT a typical physical property of amines?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1218
What is the Hofmann elimination?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1219
Which reducing agent is commonly used in reductive amination of aldehydes/keton…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1220
In reductive amination, a ketone reacts with a primary amine to form, after red…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1221
What is the smell associated with most amines?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1222
Which of the following correctly orders boiling points for similar molecular we…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1223
Why are aromatic amines weaker bases than aliphatic amines?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1224
Which substituent on aniline would increase its basicity?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1225
What is the product of the reaction of ethylamine with HCl?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1226
The reaction of an amine with an acid chloride yields:
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1227
Which of the following amines is a gas at room temperature?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1228
What is the IUPAC name for C6H5-NH-CH3?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1229
Quaternary ammonium salts have the general formula:
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1230
What is the common name for CH3CH2NH2?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1231
Which of the following statements about amine basicity is TRUE?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1232
What is the product when a 1° amine is treated with excess CH3I (methyl iodide)?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1233
What is the functional group interconversion in the reduction of an amide with …
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1234
Which of the following is an example of a heterocyclic amine?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1235
What is the major product when a tertiary amine oxide is heated?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1236
Which of the following is NOT a method of preparing primary amines?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1237
Why is the H-O-H bond angle in water (104.5°) less than the tetrahedral angle (…
Electronic Theory in Organic Chemistry View
1238
What is the product when an aromatic primary amine (aniline) is treated with ni…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1239
Which of the following is the strongest base in aqueous solution?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1240
What is the pKb of ammonia?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1241
Which of the following is a 4° (quaternary) ammonium salt?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1242
In the Gabriel synthesis, which reagent is used to alkylate phthalimide?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1243
What is the product of the reaction between an aliphatic primary amine and chlo…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1244
Secondary and tertiary amines can be distinguished from primary amines by:
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1245
What is the common name for (CH3)2CH-NH2?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1246
Which functional group is produced when a primary amine reacts with a ketone in…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1247
Which of the following amines will NOT react with Hinsberg reagent (benzenesulf…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1248
What is the product of Hofmann degradation (Hofmann rearrangement) of an amide?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1249
Which of the following is a quaternary ammonium hydroxide that upon heating und…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1250
What is the characteristic odor of isocyanides (carbylamines)?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1251
Which of the following correctly represents the basicity order of amines in aqu…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1252
Which of the following is the strongest base in aqueous solution among aliphati…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1253
What is the product of the reaction between an amine and a carboxylic acid at r…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1254
What is the IUPAC name for (CH₃CH₂)₂NH?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1255
What is the product of exhaustive methylation of a tertiary amine with excess C…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1256
What is the smell associated with most low molecular weight amines?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1257
What is the IUPAC name for C₆H₅-NH-CH₃?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1258
What is the common name for CH₃CH₂NH₂?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1259
What is the product when a 1° amine is treated with excess CH₃I (methyl iodide)?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1260
What is the functional group interconversion in the reduction of an amide with …
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1261
What is the common name for (CH₃)₂CH-NH₂?
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1262
What is the product of Hofmann degradation (Hofmann rearrangement) of a primary…
Fundamentals of Amines: Nomenclature, Isomerism, and Synthesis View
1263
Which of the following is an example of a secondary alcohol?
Nomenclature and Functional Group Classes of Organic Compounds View
1264
Which of the following is an aldehyde?
Nomenclature and Functional Group Classes of Organic Compounds View
1265
What is the correct name for the compound with a chlorine substituent on an eth…
Nomenclature and Functional Group Classes of Organic Compounds View
1266
What is the correct IUPAC name for CH₃-CH=CH-CH₃?
Nomenclature and Functional Group Classes of Organic Compounds View
1267
What is the geometry of a carbon with three attached atoms and zero lone pairs?
Electronic Theory in Organic Chemistry View
1268
What type of bond is formed by the sideways overlap of parallel p orbitals?
Electronic Theory in Organic Chemistry View
1269
What is the maximum number of electrons that can occupy a single orbital?
Electronic Theory in Organic Chemistry View
1270
Which of the following molecules has a linear geometry?
Electronic Theory in Organic Chemistry View
1271
Which of the following molecules has a trigonal planar geometry?
Electronic Theory in Organic Chemistry View
1272
Why are alkanes less reactive than alkenes?
Electronic Theory in Organic Chemistry View
1273
What is the correct name for the compound CH₃-C≡C-CH₃?
Nomenclature and Functional Group Classes of Organic Compounds View
1274
What is the IUPAC name for methyl isopropyl ketone?
Nomenclature and Functional Group Classes of Organic Compounds View
1275
What is the correct IUPAC name for the compound with structure Cl-CH₂-CH₂-OH?
Nomenclature and Functional Group Classes of Organic Compounds View
1276
What is the IUPAC name for the alcohol CH3-CH2-CH2-CH2-OH?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1277
Which of the following is the common name for 2-propanol?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1278
What is the correct IUPAC name for the compound with two OH groups on carbons 1…
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1279
Which alcohol is produced by the destructive distillation of wood?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1280
In the hydration of an alkene to form an alcohol, Markovnikov's rule states tha…
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1281
Which type of alcohol gives a ketone upon oxidation?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1282
What product is formed when a primary alcohol is oxidized with pyridinium chlor…
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1283
Why do tertiary alcohols not undergo oxidation with chromic acid?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1284
In the Lucas test, a tertiary alcohol reacts with ZnCl2/HCl within:
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1285
What is the common name for 1,2,3-propanetriol?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1286
Which alcohol is produced by the fermentation of sugars using yeast?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1287
What is the IUPAC name for the alcohol with the formula (CH3)3C-OH?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1288
What is the product of the reaction between a Grignard reagent and formaldehyde?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1289
Which reagent is used to reduce a ketone to a secondary alcohol without reducin…
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1290
What type of reaction occurs when an alcohol reacts with an active metal like s…
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1291
What is the major product of acid-catalyzed dehydration of 2-butanol?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1292
Which of the following alcohols is most soluble in water?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1293
What is the function of ZnCl2 in the Lucas test?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1294
Which alcohol, upon oxidation with Na2Cr2O7/H2SO4, gives a ketone?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1295
What is the name of the reaction where water adds to an alkene to form an alcoh…
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1296
Which of the following is a dihydric alcohol?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1297
Which of the following alcohols is tertiary?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1298
What is the name of the ester formed from ethanol and ethanoic acid?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1299
Which alcohol has the highest boiling point for a given number of carbons?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View
1300
What is the IUPAC name for CH3-CH=CH-CH2OH?
Synthesis and Reactions of Alcohols & Phenols | General Organic Chemistry View