Questions (2006)

# Question Topic Actions
501
Ethers are kept in brown bottles because
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502
Ethers are stored in brown bottles. This is because on exposure to air and ligh…
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503
Ethers can be freed from peroxides by treatment with
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504
Which of the following statements is false?
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505
Ethers react with cold concentrated H2SO4 to form
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506
Which of the following reagents readily react with ethyl methyl ether?
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507
Diethyl ether reacts with sodium metal to give
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508
Diethyl ether on heating with excess concentrated HI gives
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509
Diethyl ether reacts with excess of hot concentrated HI to form
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510
Which is the best reagent to accomplish the following conversion? CH3CH2OCH2CH3…
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511
Which of the following pairs of compounds will not form hydrogen bonds with eac…
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512
The compound with the lowest boiling point is
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513
Which of the following would have the highest boiling point?
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514
Which of the following functional group series is ranked according to increasin…
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515
The following compounds have identical molecular weights. Which would have the …
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516
Cyclic ethers with three-membered ring are called
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517
Ethylene reacts with oxygen in the presence of silver catalyst at 300°C to form
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518
Ethylene oxide reacts with HBr to give
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519
Acid-catalyzed hydrolysis of ethylene oxide yields
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520
The product of the reaction of ethylene oxide with acidic methanol is
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521
Ethylene oxide reacts with ammonia to give
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522
Which of the following is closest to the C–O–C bond angle in CH3–O–CH3?
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523
When dipentyl ether is treated with excess HI, through what type of mechanism(s…
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524
Which of the following is not a property of thiols (RSH)?
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525
Thiols are alcohol analogs in which the oxygen has been replaced by sulfur (e.g…
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526
Which of the following has the lowest boiling point?
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527
Which of the following is least soluble in water?
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528
n-Butyl bromide reacts with NaSH to give
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529
The carbon atom of a carbonyl group is
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530
Which statement about the carbonyl group is NOT true?
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531
Acetone contains
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532
Formalin is
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533
Which of the following will have the highest boiling point?
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534
What property of low-molecular weight aldehydes and ketones accounts for the ma…
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535
Primary alcohols have boiling points that are the corresponding aldehydes.
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536
The melting points of aldehydes and ketones tend to :
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537
Which action best accounts for the solubility of aldehydes and ketones in water?
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538
Ketones are prepared by the oxidation of
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539
Which of the following do you consider to be suitable for obtaining acetone (CH…
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540
Cyclopentanol undergoes oxidation to give :
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541
Which statement about the carbonyl group of ketones and aldehydes is true? I. I…
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542
Acetone reacts with HCN to form a cyanohydrin. It is an example of
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543
Which of the following reagents will react readily with both aldehydes and keto…
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544
The reaction of ethanal with one equivalent of methanol and a trace of an acid …
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545
Acetone undergoes reduction with hydrazine in the presence of NaOH to form prop…
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546
Acetone undergoes reduction with zinc amalgam in HCl to form propane. This reac…
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547
Cannizzaro reaction is not given by
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548
When formaldehyde is treated with 50% NaOH solution, it undergoes
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549
The reduction of a ketone
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550
Reduction of acetaldehyde with H2/Ni gives
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551
On reduction with LiAlH4, which of the following compounds could yield an optic…
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552
The reduction of cyclohexanone with LiAlH4 (or NaBH4) will give
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553
Aldehydes undergo oxidation with KMnO4/H+ to give
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554
Oxidation of acetaldehyde with Na2Cr2O7/H+ gives
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555
A hydrazone will result from the reaction of hydrazine with
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556
Aldehydes can be distinguished from ketones by using
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557
The appearance of a silver mirror in Tollens' test indicates the presence of :
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558
Acetaldehyde on treatment with Tollens' reagent gives a precipitate of
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559
Which of the following compounds will give a positive test with Fehling's solut…
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560
Acetaldehyde on treatment with Fehling's solution gives a precipitate of
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561
Which of the following compounds will give an iodoform test?
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562
Which of the following compounds does not give a positive iodoform test :
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563
Which of the following compounds does not give iodoform test on treatment with …
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564
An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (A)…
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565
An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (B)…
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566
An unknown compound gave a positive Tollens' test. Treatment of the unknown wit…
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567
Which of the following characterizes the reactions of aldehydes and ketones?
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568
Why do aldehydes undergo nucleophilic addition reactions while esters undergo n…
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569
Which of the following reagents can be used to reduce acetaldehyde to ethyl alc…
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570
What is the hybridization of the carbonyl oxygen in carboxylic acids?
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571
What is the hybridization and geometry of the carbonyl carbon in carboxylic aci…
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572
Organic compound (A), C4H8O, does not react with sodium or PCl5. However, it re…
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573
Check the incorrect statement :
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574
In the conversion of wine to vinegar
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575
Vinegar is a
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576
In succinic acid, HOOC(CH2)nCOOH, n is equal to
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577
In adipic acid, HOOC(CH2)nCOOH, n is equal to
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578
The compound in which hydrogen bonding is not possible is
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579
Which compound has the highest boiling point?
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580
When carboxylic acids and dicarboxylic acids have similar molecular weights, ho…
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581
The greater acidity of carboxylic acids compared to alcohols arises primarily f…
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582
Which of the following statements is false about the acid-strength of acetic ac…
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583
Arrange the following compounds in order of decreasing acidity :
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584
Which of the following is the strongest acid in aqueous solution?
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585
Which of the following compounds is most acidic?
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586
Which of the following compounds is the strongest acid?
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587
Which of the following will give acetic acid on acid-hydrolysis?
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588
Propanenitrile undergoes acid-hydrolysis to give
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589
The characteristic reaction of carboxylic acids is :
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590
Which of the following compounds will react with Tollens' reagent to give metal…
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591
Which of the following compounds on treatment with NaHCO3 will liberate CO2?
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592
Which of the following reagents will convert acetic acid into acetyl chloride?
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593
Butyric acid reacts with PCl5 to give
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594
Acetic acid undergoes reduction with LiAlH4 to give
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595
Acetic acid reacts with methyl alcohol in the presence of an acid catalyst to g…
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596
Calcium acetate on strong heating gives
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597
Amides undergo hydrolysis under acidic conditions to give
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598
CH3(CH2)4COONa is the sodium salt of hexanoic acid. The water solubility of thi…
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599
Which of the following compounds has the lowest boiling point?
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600
Which of the following is the correct ranking in decreasing order of relative B…
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