Questions (2006)

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401
There are 8 isomers that have the molecular formula C5H11Br. How many of these …
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402
Which of the following is the best leaving group?
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403
Which of the following statements is correct for a saturated alkyl halide?
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404
Which of the following best describes the carbon-chlorine bond of an alkyl chlo…
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405
Which of the following is a secondary alkyl halide?
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406
How should CH3CHClCH2CH3 be classified?
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407
Which of the following will have the lowest boiling point?
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408
Which of the following is not correct concerning substitution and elimination r…
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409
Which of the following statements concerning SN2 reactions of alkyl halides is …
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410
Which of the following correctly reflects relative stabilities of carbocations?
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411
Which of the following species is most reactive in a SN2 reaction?
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412
Which is the strongest acid?
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413
Which of the following is the strongest nucleophile in an aqueous solution?
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414
Which of the following is the best nucleophile in water?
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415
Which of the following compounds will undergo an SN2 reaction most readily?
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416
Which of the following is the rate law for SN1 mechanisms?
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417
Which of the following factors has no effect on the rate of SN1 reactions?
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418
Which is the most reactive alkyl halide in a SN1 reaction?
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419
Which of the following halides is most reactive in an E2 reaction with sodium m…
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420
Which of the following halides is least reactive in an E2 reaction with sodium …
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421
Dehydrohalogenation of 2-bromobutane in the presence of a strong base proceeds …
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422
Predict the two most likely mechanisms for the reaction of 2-iodohexane with so…
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423
Predict the two most likely mechanisms which occur when 2-iodohexane is heated …
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424
Grignard reagents do not show any reaction with
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425
The Grignard reagent, CH3CH2MgBr, can be used to prepare
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426
Which is the best reagent to accomplish the following conversion?
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427
What is the major product of the following reaction?
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428
Ethylmagnesium iodide reacts with formaldehyde to give a product which on acid-…
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429
Ketones react with Grignard reagents to form an addition product which on hydro…
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430
Which of the following compounds will react with methylmagnesium bromide to giv…
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431
Phenylmagnesium bromide reacts with acetaldehyde to form an addition product wh…
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432
Which of the following alcohols can be prepared by the reaction of methyl forma…
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433
The number of structural isomers of alcohols with molecular formula C3H7OH is
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434
The number of structural isomers of alcohols with molecular formula C4H9OH is
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435
Why do alcohols have boiling points much higher than hydrocarbons of similar mo…
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436
The high boiling points of alcohols, as compared to the corresponding alkanes, …
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437
Which of the following has the highest boiling point?
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438
Rank the following substances in order of increasing boiling point (lowest → hi…
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439
Which of the following compounds is the least soluble in water?
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440
Methanol is known as :
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441
Rectified spirit is
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442
Grain alcohol is another name for
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443
Lucas reagents is
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444
Lucas test is used to determine the type of
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445
Which of the following gives positive Iodoform test :
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446
Which of the following reagents will replace –OH group by a halogen atom?
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447
The compound which reacts most readily with Lucas reagent is
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448
Which of the following compounds reacts slowest with Lucas reagent at room temp…
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449
Which of the following compounds will react fastest with Lucas reagent?
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450
Which of the following compounds reacts fastest with HBr?
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451
When ethanol is treated with sodium metal :
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452
Which of the following alcohols will give a yellow precipitate of iodoform with…
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453
Ethyl alcohol can react with concentrated H2SO4 to give
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454
Ethanol on heating with concentrated H2SO4 at 170°C gives
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455
The major product of acid-catalyzed dehydration of 2-butanol is :
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456
Which is the best reagent for carrying out the following conversion?
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457
Which of the following reaction mixtures will give an organic product which is …
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458
Hydroboration-oxidation of propene gives :
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459
Hydroboration-oxidation of 2-Methylpropene gives
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460
Which of the following compounds will not be easily oxidized?
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461
Which of the following is most resistant to oxidation?
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462
Oxidation of a primary alcohol with produces
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463
Oxidation of a secondary alcohol with K2Cr2O7/H+ produces
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464
Isopropyl alcohol can be converted to acetone by treatment with
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465
Which of the bonds in Ethyl alcohol (CH3CH2OH) will undergo heterolytic bond fi…
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466
The mechanism of dehydration of an alcohol to give an alkene involves formation…
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467
The mechanism of dehydration of an alcohol to give an ether involves formation …
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468
The acid-catalyzed dehydration mechanism for alcohols is best described as a(n)…
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469
When ethanol is heated with concentrated H2SO4, a gas is produced. Which of the…
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470
What is the functional group in an alcohol?
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471
What is the IUPAC name for the following structure? CH3CH(CH3)CH2CH(OH)CH3
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472
Explain why the water molecule has a bent shape and a bond angle less than 109.…
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473
Which of the following compounds does not have the molecular formula C6H14O?
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474
Which of the following is a secondary alcohol?
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475
Which of the following is sec-butyl alcohol?
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476
What is the hybridization of the oxygen atom in CH3CH2OH?
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477
Where are the two lone pairs of electrons of the oxygen atom in an alcohol mole…
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478
What is the strongest intermolecular force present in liquid ethanol?
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479
Which of the following is the best method for preparing CH3Br?
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480
Which of the following reagents can be used to oxidize 1° alcohols to aldehydes?
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481
In cold countries ethylene glycol is added to water in car radiators. This help…
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482
Ethylene oxide undergoes acid-hydrolysis to form
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483
Ethylene glycol undergoes oxidation with hot acidic KMnO4 to form :
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484
Ethylene glycol reacts with excess of PCl5 to give
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485
1,2-Ethanediol reacts with anhydrous zinc chloride to form
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486
When ethylene glycol is heated with concentrated HNO3, it forms
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487
Which of the following is used as an antifreeze?
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488
When glycerol is heated with oxalic acid at 260°C, it gives
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489
When glycerol is heated with potassium hydrogen sulfate (KHSO4), it forms
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490
Glycerol on warming with a small amount of hydriodic acid gets converted to
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491
When glycerol is treated with a mixture of concentrated HNO3 + H2SO4, it forms
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492
In the manufacture of dynamite, one of the chemicals used is
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493
Which of the following compounds is least soluble in water?
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494
Compound (A) reacts with sodium metal to form one mole of H2. The compound (A) …
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495
Ethers are
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496
Ethanol is isomeric with
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497
Diethyl ether and methyl propyl ether are
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498
The reaction of a sodium alkoxide with an alkyl halide is called
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499
Ethyl bromide reacts with sodium methoxide to form
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500
Ethyl alcohol reacts with concentrated H2SO4 at 140°C to form
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