Objective Questions
All objective questions for CHM 102
Questions (2006)
| # | Question | Topic | Actions |
|---|---|---|---|
| 601 |
Acetyl chloride undergoes nucleophilic substitution at a faster rate than methy…
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| 602 |
Esters and amides are most easily made by nucleophilic acyl substitution reacti…
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| 603 |
Which of the following conditions will drive the equilibrium of the Fischer est…
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| 604 |
Which of the following statements describes the first step in the mechanism of …
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| 605 |
Ammonium acetate on strong heating gives
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| 606 |
Which reaction does not yield an ester as one of the products?
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| 607 |
Silver acetate reacts with Br2 to form methyl bromide, carbon dioxide, and AgBr…
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| 608 |
Hunsdiecker reaction is used for the preparation of
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| 609 |
A compound undergoes reduction with LiAlH4. It also dissolves in aqueous NaOH f…
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| 610 |
Acid chlorides undergo reduction to the corresponding aldehydes on treatment wi…
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| 611 |
Acetic anhydride is obtained by the reaction of :
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| 612 |
Acetic anhydride reacts with ethanal to give
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| 613 |
Acetamide on heating with P2O5 gives :
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| 614 |
Acetamide is a much weaker base than ammonia. This is because
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| 615 |
Which of the following statements is False about acetamide?
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| 616 |
The C—C—O bond angle in is approximately
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| 617 |
Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and am…
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| 618 |
Which of the following acid-derivatives are most stable?
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| 619 |
Acetamide can be converted into methylamine by
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| 620 |
Acetamide on reduction with LiAlH4 gives
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| 621 |
By which of the following methods can CH3CONH2 be converted to CH3CN?
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| 622 |
Which of the following reagents will react with acetamide to form methylamine?
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| 623 |
Which of the following compounds does not form a salt with dilute HCl?
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| 624 |
Propionamide on heating with a mixture of bromine and sodium hydroxide gives
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| 625 |
What happens when urea is treated with hydrazine?
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| 626 |
Carbonyl chloride reacts with ammonia to give
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| 627 |
Which of the following is not a constituent of normal urine?
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| 628 |
Esters can be formed by nucleophilic substitution reactions of :
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| 629 |
The conversion is called :
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| 630 |
Hydrolysis of an ester can be accomplished by :
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| 631 |
Basic-hydrolysis of esters is called
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| 632 |
Base-catalyzed condensation of two ester molecules to form an alcohol and β-ket…
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| 633 |
Ethyl acetoacetate undergoes acid-hydrolysis with dilute HCl to form
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| 634 |
The ethyl derivative of acetoacetic ester on basic-hydrolysis gives
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| 635 |
Ethyl acetate on heating with sodium ethoxide gives
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| 636 |
When ethyl acetoacetate is subjected to ketonic hydrolysis, the ketone obtained…
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| 637 |
Ethyl acetoacetate reacts with phenylhydrazine to give
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| 638 |
Keto-enol tautomerism is shown by
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| 639 |
Fatty acids are
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| 640 |
Sodium or potassium salts of fatty acids are called
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| 641 |
Soap is
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| 642 |
A wax is
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| 643 |
Fats and oils are
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| 644 |
Fats differ from waxes in that fats have :
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| 645 |
Oleic acid is a fatty acid containing
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| 646 |
Both stearic acid and linoleic acid have 18 carbons. Linoleic acid is unsaturat…
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| 647 |
Liquid oils can be converted to solid fats by
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| 648 |
Partial hydrogenation of vegetable oils in the presence of Ni catalyst at 200°C…
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| 649 |
Alkaline hydrolysis of oils (or fats) is called :
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| 650 |
Saponification of a fat
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| 651 |
Which of the following compounds will not be classified as lipids?
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| 652 |
Synthetic detergents can be represented by the following general formula
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| 653 |
The degree of unsaturation of a fat can be determined by means of its
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| 654 |
Which of the following statements is not true about fatty acids?
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| 655 |
Which of the following best explains why the melting points of saturated fats i…
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| 656 |
Which of the following terms best describes the compound below? CH3(CH2)12CO2H
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| 657 |
Which of the following terms best describes the compound below? CH3(CH2)7CH=CH(…
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| 658 |
Which of the following statements best describes the structure of waxes?
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| 659 |
Which of the following terms best describes the compound below? CH3(CH2)26CO2CH…
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| 660 |
Which of the following statements is not true about triacylglycerols?
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| 661 |
Triglycerides which are solids or semisolids at room temperature are called .
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| 662 |
Which of the following statements is not true about phospholipids?
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| 663 |
The compound methylamine, H3C–NH2, contains a C–N bond. In this bond, which of …
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| 664 |
Triethylamine [(CH3CH2)3N] is a molecule in which the nitrogen atom is hybridiz…
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| 665 |
The N–H bond in the ammonium ion, NH4+, is formed by the overlap of what two or…
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| 666 |
What is the hybridization of the nitrogen atom in CH3NH2?
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| 667 |
What is the hybridization of the carbon atom in CH3NH2?
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| 668 |
What type of intermolecular interactions does (CH3CH2)2NH undergo?
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| 669 |
Assuming roughly equivalent molecular weights, which of the following would hav…
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| 670 |
Which of the following statements is false about primary amines?
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| 671 |
Which of the following statements is false about secondary amines?
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| 672 |
The hybridization of nitrogen in an amine is
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| 673 |
Which type of amine produces N2 when treated with HONO?
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| 674 |
A sample of pure amine molecules is found to possess no intermolecular H-bondin…
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| 675 |
Which amine is NOT soluble in water?
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| 676 |
Consider a 1°, 2° and 3° amine, all of equivalent molecular weight. Which amine…
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| 677 |
Which compound has the highest boiling point? 1. CH3CH2CH3 2. CH3CH2OH 3. CH3CH…
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| 678 |
Amines are generally classified as
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| 679 |
Acetamide reacts with Br2/NaOH to give
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| 680 |
Acetonitrile undergoes reduction with LiAlH4 to form :
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| 681 |
Reduction of an imine will give an
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| 682 |
Which of the following is most basic?
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| 683 |
Alkyl halides react with ammonia in the presence of base to form :
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| 684 |
The major product of the following reaction is :
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| 685 |
Aliphatic primary amines react with cold nitrous acid to form
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| 686 |
Methylamine reacts with nitrous acid to form
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| 687 |
A nitrile can be made by dehydrating an amide. However, for this reaction to oc…
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| 688 |
Which of the following amines react with nitrous acid to form nitrosoamine?
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| 689 |
Which of the following does not react with acyl chlorides to form amides :
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| 690 |
Hinsberg's reagent is
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| 691 |
Which of the following compounds will dissolve in aqueous NaOH after undergoing…
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| 692 |
Which of the following compounds does not react with acetyl chloride?
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| 693 |
A primary amine can be identified by using
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| 694 |
Carbylamine test is given by
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| 695 |
Which of the following describes the side chain for Alanine?
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| 696 |
Which of the following describes the side chain for Valine?
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| 697 |
Which of the following describes the side chain of Leucine?
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| 698 |
Which of the following amino acids has an aliphatic R group?
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| 699 |
Which of the following amino acids has an aromatic R group?
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| 700 |
Which of the following amino acids has a sulfur in the R group?
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