Questions (2006)

# Question Topic Actions
601
Acetyl chloride undergoes nucleophilic substitution at a faster rate than methy…
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602
Esters and amides are most easily made by nucleophilic acyl substitution reacti…
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603
Which of the following conditions will drive the equilibrium of the Fischer est…
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604
Which of the following statements describes the first step in the mechanism of …
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605
Ammonium acetate on strong heating gives
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606
Which reaction does not yield an ester as one of the products?
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607
Silver acetate reacts with Br2 to form methyl bromide, carbon dioxide, and AgBr…
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608
Hunsdiecker reaction is used for the preparation of
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609
A compound undergoes reduction with LiAlH4. It also dissolves in aqueous NaOH f…
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610
Acid chlorides undergo reduction to the corresponding aldehydes on treatment wi…
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611
Acetic anhydride is obtained by the reaction of :
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612
Acetic anhydride reacts with ethanal to give
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613
Acetamide on heating with P2O5 gives :
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614
Acetamide is a much weaker base than ammonia. This is because
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615
Which of the following statements is False about acetamide?
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616
The C—C—O bond angle in is approximately
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617
Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and am…
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618
Which of the following acid-derivatives are most stable?
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619
Acetamide can be converted into methylamine by
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620
Acetamide on reduction with LiAlH4 gives
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621
By which of the following methods can CH3CONH2 be converted to CH3CN?
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622
Which of the following reagents will react with acetamide to form methylamine?
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623
Which of the following compounds does not form a salt with dilute HCl?
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624
Propionamide on heating with a mixture of bromine and sodium hydroxide gives
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625
What happens when urea is treated with hydrazine?
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626
Carbonyl chloride reacts with ammonia to give
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627
Which of the following is not a constituent of normal urine?
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628
Esters can be formed by nucleophilic substitution reactions of :
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629
The conversion is called :
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630
Hydrolysis of an ester can be accomplished by :
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631
Basic-hydrolysis of esters is called
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632
Base-catalyzed condensation of two ester molecules to form an alcohol and β-ket…
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633
Ethyl acetoacetate undergoes acid-hydrolysis with dilute HCl to form
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634
The ethyl derivative of acetoacetic ester on basic-hydrolysis gives
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635
Ethyl acetate on heating with sodium ethoxide gives
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636
When ethyl acetoacetate is subjected to ketonic hydrolysis, the ketone obtained…
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637
Ethyl acetoacetate reacts with phenylhydrazine to give
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638
Keto-enol tautomerism is shown by
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639
Fatty acids are
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640
Sodium or potassium salts of fatty acids are called
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641
Soap is
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642
A wax is
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643
Fats and oils are
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644
Fats differ from waxes in that fats have :
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645
Oleic acid is a fatty acid containing
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646
Both stearic acid and linoleic acid have 18 carbons. Linoleic acid is unsaturat…
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647
Liquid oils can be converted to solid fats by
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648
Partial hydrogenation of vegetable oils in the presence of Ni catalyst at 200°C…
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649
Alkaline hydrolysis of oils (or fats) is called :
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650
Saponification of a fat
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651
Which of the following compounds will not be classified as lipids?
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652
Synthetic detergents can be represented by the following general formula
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653
The degree of unsaturation of a fat can be determined by means of its
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654
Which of the following statements is not true about fatty acids?
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655
Which of the following best explains why the melting points of saturated fats i…
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656
Which of the following terms best describes the compound below? CH3(CH2)12CO2H
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657
Which of the following terms best describes the compound below? CH3(CH2)7CH=CH(…
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658
Which of the following statements best describes the structure of waxes?
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659
Which of the following terms best describes the compound below? CH3(CH2)26CO2CH…
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660
Which of the following statements is not true about triacylglycerols?
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661
Triglycerides which are solids or semisolids at room temperature are called .
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662
Which of the following statements is not true about phospholipids?
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663
The compound methylamine, H3C–NH2, contains a C–N bond. In this bond, which of …
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664
Triethylamine [(CH3CH2)3N] is a molecule in which the nitrogen atom is hybridiz…
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665
The N–H bond in the ammonium ion, NH4+, is formed by the overlap of what two or…
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666
What is the hybridization of the nitrogen atom in CH3NH2?
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667
What is the hybridization of the carbon atom in CH3NH2?
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668
What type of intermolecular interactions does (CH3CH2)2NH undergo?
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669
Assuming roughly equivalent molecular weights, which of the following would hav…
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670
Which of the following statements is false about primary amines?
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671
Which of the following statements is false about secondary amines?
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672
The hybridization of nitrogen in an amine is
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673
Which type of amine produces N2 when treated with HONO?
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674
A sample of pure amine molecules is found to possess no intermolecular H-bondin…
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675
Which amine is NOT soluble in water?
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676
Consider a 1°, 2° and 3° amine, all of equivalent molecular weight. Which amine…
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677
Which compound has the highest boiling point? 1. CH3CH2CH3 2. CH3CH2OH 3. CH3CH…
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678
Amines are generally classified as
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679
Acetamide reacts with Br2/NaOH to give
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680
Acetonitrile undergoes reduction with LiAlH4 to form :
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681
Reduction of an imine will give an
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682
Which of the following is most basic?
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683
Alkyl halides react with ammonia in the presence of base to form :
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684
The major product of the following reaction is :
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685
Aliphatic primary amines react with cold nitrous acid to form
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686
Methylamine reacts with nitrous acid to form
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687
A nitrile can be made by dehydrating an amide. However, for this reaction to oc…
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688
Which of the following amines react with nitrous acid to form nitrosoamine?
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689
Which of the following does not react with acyl chlorides to form amides :
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690
Hinsberg's reagent is
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691
Which of the following compounds will dissolve in aqueous NaOH after undergoing…
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692
Which of the following compounds does not react with acetyl chloride?
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693
A primary amine can be identified by using
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694
Carbylamine test is given by
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695
Which of the following describes the side chain for Alanine?
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696
Which of the following describes the side chain for Valine?
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697
Which of the following describes the side chain of Leucine?
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698
Which of the following amino acids has an aliphatic R group?
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699
Which of the following amino acids has an aromatic R group?
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700
Which of the following amino acids has a sulfur in the R group?
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